Preparation of Silicon Nanowires Photocathode for Photoelectrochemical Water Splitting

نویسندگان

چکیده

A metal-assisted chemical etching process employing p-type silicon wafers with varied durations is used to produce nanowires. Silver nanoparticles prepared by deposition are utilized as a catalyst in the formation of Images from field emission scanning electron microscopy confirmed that diameter SiNWs grows when duration increased. The photoelectrochemical cell's characteristics were investigated using nanowires working electrodes. Linear sweep voltammetry (J-V) measurements on p-SiNWs photocurrent density rose 0.20 mA cm-2 0.92 increased 15 30 min. conversion efficiency (ƞ) was 0.47 for 15-minute time and 0.75 30-minute time. cyclic (CV) experiments performed at various scan rates validated faradic behavior p-SiNWS min etching. Because slow ion diffusion rate, capacitance decreased increasing rate. Mott-Schottky (M-S) investigation showed significant carriers concentration 3.66×1020 cm-3. According results electrochemical impedance spectroscopy (EIS), photocathode had charge transfer resistance 25.27 Ω, which low enough enhance interfacial transfer.

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ژورنال

عنوان ژورنال: Iraqi Journal of Physics

سال: 2022

ISSN: ['2664-5548', '2070-4003']

DOI: https://doi.org/10.30723/ijp.v20i4.1070